Sunday, May 11, 2014

One of the largest atomic nuclei known could lead to the discovery of elements that do not immediately decay...

The linear accelerator at the GSI laboratory in Germany accelerated calcium ions to 10 percent the speed of light to create element 117.

Physicists have created one of the heaviest elements yet, an atom with 117 protons in its nucleus. This jumbo-sized atom sits on the outer reaches of the periodic table where bloated nuclei tend to become less and less stable. Element 117’s existence gives scientists hope, however, that they are getting closer to discovering a rumored “island of stability” where nuclei with so-called magic numbers of protons and neutrons become long-lived.

Elements heavier than uranium (with 92 protons) are not usually found in nature, but they can be forced into existence in laboratories. The trouble is: the larger an atomic nucleus gets, the more its protons repel one another with their positive charges, making it, in general, less stable, or more radioactive. Element 117, for example, has a half-life of about 50 thousandths of a second, meaning that within that time about half of it will decay into a lighter element.

A U.S.–Russian team first created element 117 in 2010 at the Joint Institute for Nuclear Research in Dubna, Russia. The element is still considered unofficial, and has not yet been formally accepted and added to the periodic table by the International Union of Pure and Applied Chemistry (IUPAC). The new appearance of 117, in experiments by the GSI Helmholtz Center for Heavy Ion Research in Darmstadt, Germany, should help the element gain official recognition. “In contrast to the first discovery, we are a different team at a different place using a different device,” says Christoph Düllmann, who led the GSI collaboration. “I think within the scientific community that will change the view on element 117 from an element that has been claimed to be observed to an element that is confirmed.”

To create 117, with the temporary periodic table placeholder name ununseptium, the researchers smashed calcium nuclei (with 20 protons apiece) into a target of berkelium (97 protons per atom). The experiment was so difficult in part because berkelium itself is tough to come by. “We had to team up with the only place on the planet where berkelium can be produced and isolated in significant quantities,” Düllmann says. That place is the Oak Ridge National Laboratory in Tennessee, which has a nuclear reactor that can create the rare element with a half-life of 330 days. It took the facility about two years to build up a large enough stock of berkelium for the experiment; when about 13 milligrams had accumulated, Oak Ridge scientists shipped it off to Germany for the next stage of the project. At GSI, researchers accelerated calcium ions to 10 percent light-speed and sent them colliding into the berkelium. If a calcium and berkelium nucleus collided head-on, occasionally the two nuclei would stick together, fusing to form a new element with a combined total of 117 protons. “We get about one atom per week,” Düllmann says.

The scientists did not observe element 117 directly. Instead, they searched for its daughter products after it radioactively decayed by emitting alpha particles—helium nuclei with two protons and two neutrons. “The heavy nuclei makes an alpha decay to produce element 115, and this also decays by alpha decay,” says Jadambaa Khuyagbaatar of GSI, lead author of a paper reporting the results published May 1 inPhysical Review Letters.

After a few more steps in this decay chain, one of the nuclei produced is the isotope lawrencium 266—a nucleus with 103 protons and 163 neutrons that had never been seen before. Previously known isotopes of lawrencium have fewer neutrons, and are less stable. This novel species, however, has an astonishingly long half-life of 11 hours, making it one of the longest-lived superheavy isotopes known to date. “Perhaps we are at the shore of the island of stability,” Düllmann says.

No one knows for sure where this island lies, or even if it exists at all. Theory suggests that the next magic numbers beyond those known are around 108, 110 or 114 protons, and 184 neutrons. These configurations, according to calculations, could lead to special properties that allow atoms to survive much longer than similar species. “All existing data for elements 116, 117 and 118 do confirm that lifetimes increase as one goes closer to the neutron number 184, says theorist Witold Nazarewicz of Oak Ridge, who was not involved in the study. “This is encouraging.”

Superheavy magic nuclei may turn out to have interesting shapes that confer stability, such as a so-called bubble configuration with a hole in the middle. “These have never been discovered yet, but the region that is being explored now is really on the edge of bubble territory,” Nazarewicz says.

If an island of stability does exist, there is no limit to how long its nuclei may last. They could turn out to be stable enough to be found in nature, albeit in such small quantities that we have not seen them yet. Numerous searches are on for evidence of these superheavy species already in existence, perhaps having formed through powerful cosmic events such as the merging of two neutron stars. Although none have been found so far, scientists are holding out hope that evidence for the island of stability is just around the corner, one way or another.

May 7, 2014 |By Clara Moskowitz

Sunday, May 4, 2014

Lesson Plans May 5th - May 9th

Lesson Plans Adv Chemistry May 5th - 9th

Monday:
1.  Continue notes on naming organic compounds thru isomers
2.  Finish Additional Probs II for tomorrow
3.  Worksheet II for Weds

Tuesday:
1.       Practice Quiz
2.       Quizzes over alkanes on Weds and Thurs
3.       Grade Additional Problems II
4.       Worksheet II due tomorrow
5.       Notes on alkenes and alkynes
6.       Alkenes and alkynes, alkenes and alkynes again due Thursday

Weds:
1.       Quiz I – alkanes
2.       Intermolecular Forces Lab
3.       Model Kit Lab I

Thursday:
1.       Quiz II – alkanes
2.       Grade Worksheet II
3.       Alkene/Alkynes due
4.       Quiz tomorrow over alkenes and alkynes
5.       Continue Labs

Friday:
1.       Grade alkenes/alkynes
2.       Quiz over them
3.       Complete Labs

Lesson Plans Chemistry May 5th - 9th

Monday:
1.  Single Replacement Lab
2.  Balancing III and IV due

Tuesday:
1.  works bomb demo 8th hour
2.  grade balancing II
3.  quiz I over balancing

Weds:
1.  go over quiz I
2.  continue notes over identifying reactions
3.  balancing III graded tomorrow
4.  id worksheet #1due Friday

Thursday:
1.  grade balancing III
2.  continue notes over identifying reactions
3.  id worksheet #2due Monday

Friday:
1.  grade balancing IV
2.  continue notes over identifying reactions

Lesson Plans AP Chemistry May 5th - 9th

Monday:  AP Test

Tuesday:  t-shirt design

Weds:  chemical preparation day

Thursday:  start organic notes over ethers and alcohols


Friday:  organic notes over carboxylic acids and esters

Wednesday, April 30, 2014

Lesson Plans April 28- May 2nd

Chemistry I Lesson Plans April 28th – May 2nd

Monday:
1.  Notes over balancing equations
2.  Finish ch 6 test
3.  Balancing I and II due Weds

Tuesday:
1.      Continue notes over balancing and types of  reactions
2.      Balancing I and II due tomorrow
3.      Balancing III and IV due Friday

Weds:
1.  Notes through single replacement reactions
2.  Balancing I and II due
3.  Balancing III and IV due Friday

Thurs:
1.  Thermite Demo
2.  Continue notes over types of reactions

Friday:
1.  Works Bomb Demo
2.  Worksheets III and IV due
3.  Quiz Tuesday over balancing equations
4.  Single Replacement Pre-Lab for Monday’s Lab

Lesson Plans Adv Chemistry April 28th - May 9th
Students will be able to recognize, name, and draw alkanes, alkenes, and alkynes and understand how the structure affects the molecular properties of the molecules and their uses.

Monday:   Acid/Base Test

Tuesday:
1.      Notes on organic chemistry and hydrocarbon alkanes
2.      Practice Probs I and WI on alkanes due Thursday

Weds:
1.      Continue notes on alkanes – naming them
2.      PPI and WI due tomorrow
3.      Quiz on 10 alkanes Friday

Thurs:   
1.  Grade PPI and WI
2.  Notes on naming and reconstructing alkanes
3.  Additional Probs II #2 only for Monday

Friday:
1.  Quiz on 10 alkanes
2.  Continue notes on naming and drawing hydrobarbons
3.  Additional Probs II finish for Tuesday

Lesson Plans AP Chemistry April 28th - May 9th
Students will prepare for the AP Test which is Monday.

Monday:   finish acid/base review

Tuesday:  experimental chemistry review

Weds:  Practice Diagnostic test I and grade in class

Thurs:  Practice Diagnostic test II and grade in class


Friday:  Review crib notes for test on Monday

Friday, April 11, 2014

Lesson Plans 22nd - 25th

Lesson Plans April 22nd - 25th

Chemistry I:  This week students will be able to review information from the unit in preparation for the unit test.   It is a crazy week with Juniors taking the ACT and PSAE test.

Monday:  no school
Tuesday:
1.  WebMO I due
2.  grade 60 point review sheet on bonding
3.  90 point review due also
Wednesday and Thursday:  ACT for Juniors
1.  Finish WebMO II
2.  Lewis quiz if absent last week
3.  Make sure your 90 point review is with Mrs. Block so she can grade it
Friday: 
1.  look over 90 point review sheet
2.  Chemical Bonding Exam

Chemistry II:  This week students will be able to review information from the unit in preparation for the unit test.   It is a crazy week with Juniors taking the ACT and PSAE test.

Monday:  no school
Tuesday:
1.  Ka quiz and homework back
2.  grade acid base review
3.  test on Friday
Wednesday and Thursday:  ACT for Juniors
Friday:  Acid Base Exam

AP Chemistry:
Students are finishing reviews in preparation for the AP test which will be May 5th.

Monday:  no school
Tuesday:
1.  practice tests are due – graded
2.  thermochemistry review
3.  outline thermochemistry chapter and take practice test on that chapter due Friday
Weds:  Diagnostic test #2 – take and score and turn in
Thursday:  Diagnostic test #3 – take and score and turn in
Friday:  film “the Pack Attack” commercial
1.  thermochemistry outline and practice test due
2.  acid/base review

3.  outline acid base chapter and take practice test on that chapter due Friday

Monday, April 7, 2014

Lesson Plans April 7th - 11th

Chemistry I Lesson Plans April 7-11th

This week we are continuing our study of molecular geometry and using student created Lewis structures and those created in the computational chemistry program WebMO to analyze properties of these molecules.  Students will be able to predict geometry types based on both the VSEPR and Hybridization Theories as well as visualize the electron pair domains, geometries, and hybridizations of many different molecules.  Students will be preparing for their ch 6 test which will be sometime after Spring Break.

Monday:
1.  Lewis III worksheet due
2.  finish WebMO – due Thursday
3.  pick up naming review for test – due Wednesday
4.  Lewis II quiz on Wednesday

Tuesday:  sophomores gone
1.  finish WebMO I if needed
2.  start WebMO II
3.  finish naming review for test due tomorrow
4.  Lewis II quiz tomorrow

Weds:
1.  Lewis II quiz
2.  finish notes on unit
3.  naming review due tomorrow for test
4.  test Friday after break

Thursday:
1.  grade naming review
2.  finish WebMO activities

Friday:
1.  grade Lewis III worksheet
2.  Juniors - work on unit review – due Thursday after break
3.  Test Friday after break









Adv Chemistry  Lesson Plans April 7-11th

Students will understand how to calculate pH of a weak acid with the help of an ICE table.  We will be taking the chapter test after break so the acid/base review needs to be completed.

Monday:
1.  ICE table notes
2.  titration review due
3.  Acid/base review due Thursday

Tuesday: 
1.  grade titration review
2.  ICE Table notes
3.   Ka problems due Friday

Weds:
1.  finish ICE notes
2.  work on Ka problems
3.  quiz I Friday over Ka

Thursday:
1.  grade review sheet
2.  Ka worksheet and quiz due tomorrow

Friday:
1.  grade Ka worksheet
2.  Ka quiz 1
3.  Ka quiz 2 Tuesday after break
4.  Test on Friday after break















AP Chemistry  Lesson Plans April 7-11th

Students will understand how to find the rate law expression given the rate constant in both an elementary and multiple step reaction. 

Monday:
1.  finish notes on elementary rate law problems
2.  begin working on ch 11 outline homework – due Friday

Tuesday:
1.  discuss the rate determining step in kinetics
2.  begin homework Kinetics worksheet I – due Thursday
3.  ch 11 outline homework due Friday
4.  rates of reaction lab due Friday

Weds:
1.  finish rates of reaction lab – due Friday
2.  continue working on chapter homework

Thursday: 
1.  grade kinetics worksheet I
2.  finish ch homework for tomorrow


Friday:  AP practice test

Sunday, March 30, 2014

Lesson Plans March 31st -April 4th

Lesson Plans Chemistry I March 31st -April 4th
Students will continue to practice drawing Lewis structures.  By the end of the week, they will understand how to relate these structures to molecular properties by analyzing the geometry of the Lewis structure as well as the bond lengths, bond angles, electron pair domains, and hybridizations.  The computational program WebMO will help them visualize these concepts in 3D.

Monday:
1.      Continue notes on Lewis Structures – sigma and pi bonds and polyatomic ions
2.      Lewis I due tomorrow
3.      Lewis II due Weds
Tuesday: 
1.      Grade Lewis I worksheet
2.      Notes on VSEPR and electron pair domains
3.      Lewis II due tomorrow
4.      Lewis III due Thursday
Wednesday: 
1.      Grade Lewis II worksheet
2.      Lewis quiz tomorrow
3.      Notes on hybridization and metallic bonding
4.      Lewis III due tomorrow
Thursday:
1.      Grade Lewis III
2.      Lewis quiz
3.      Finish notes if needed
4.      Chapter 6 review due Tuesday
Friday:  WebMO I activity on bond angles and lengths and hybridization


this drawing of nitrogen dioxide in WebMO helps students analyze the molecule's bond lengths, angles, and hybridizations as well as how these aspects affect the molecule's properties

Lesson Plans Adv. Chemistry  March 31st -April 4th
By the end of the week, students will be able to interpret pH titration graphs and understand that there is a difference between a strong acid/strong base titration and those with weak acids or weak bases.  Using an ICE table helps in the mathematical process in solving such weak acid problems.  Finding the Ka value of an acid  using an ICE table is very important in understanding the concept of equilibrium , which is one of the big topics in Chemistry.

Monday:
 1.  grade titration problems II
2.  titration quiz
3.  titration curve worksheet due Weds
4.  ICE table examples from  notes
Tuesday:
 1.  ICE table examples from notes
2.  Ka worksheet due Friday
Wednesday:
 1.  grade titration curves worksheet
2.  titration curves quiz
3.  acid base review due Monday
Thursday
 1.  ICE table examples from notes
2.  Ka worksheet due tomorrow
3.  Ka quiz tomorrow
Friday:
1.  grade the Ka worksheet
2.  Ka quiz
3.  acid base review due Monday



Lesson Plans AP Chemistry  March 31st -April 4th
Students will finish our study of equilibrium which will be revisited in their review of the acid/base unit and thermodynamics unit.  By the end of the week, students will begin to understand the concept of reaction rates as we cover this topic and begin our first lab of the unit.  A further exploration of this concept will be continued next week.


the iodine clock reaction is a standard lab for observing order or reaction rates

Monday:
1.  Probs #11-17 due
2.  ch 11 rates of reaction overdue!
3.  finish march madness periodic table game
4.  Cliff’s homework set due Weds
Tuesday:
1.  Vitamin C Clock Reaction Lab
2.  Cliff’s homework due tomorrow
Weds:
1.  AP quiz over equilibrium – multiple choice and free response
2.  Cliff’s homework due
3.  March  Madness due
Thursday:
1.  rates of reaction ch 11 lecture
2.  iodine clock reaction lab part I
Friday:
1.  rates of reaction ch 11 lecture over
2.  iodine clock reaction lab part II


Sunday, March 23, 2014

Lesson Plans for March 24 thru 28

Chemistry I Lesson Plans March 24-28
This week we are finishing up our Penny Lab where we looked at why you can place over 150 drops of water on a penny.  We used a computational chemistry program to draw water and other solutions and look at their properties (webmo.net).  After two weeks of naming and writing ionic and covalent compounds, we are ready to start drawing their Lewis structures.  This is a very important unit as it is the groundwork for learning what reactions take place in our next chapter – where the real chemistry can begin……
 
webmo drawing of acetone (nail polish remover)


Monday:
1.       Grade writing 2
2.       Finish Penny Lab discussion – no graphs this year, labs due Friday
3.       Naming and Writing 3 due tomorrow
4.       Quiz Weds over naming and writing
5.       Notes on bond types and Lewis Structures
Tuesday:
1.       Grade naming compounds 3
2.       Notes on Lewis continued
3.       Lewis I due Thursday
4.       Quiz over naming and writing tomorrow
Weds:
1.       Grade writing compounds 3
2.       Quiz over naming and writing compounds
3.       Continue notes on drawing Lewis structures
4.       Lewis I due Friday
5.       Penny Lab due Friday
      Thursday:
1.   Discuss quiz
2.   Lewis I due tomorrow
3.   Double and triple bonds in Lewis structures - notes

Friday:
1.  Grade Lewis I
2.  Continue notes over VSEPR theory
3.  Penny Lab due
4.  Lewis II due Tuesday

Adv. Chemistry Lesson Plans March 24-28
This week we are finishing up our titration portion of the acid/base unit.  We used a virtual titration lab last week to practice titrating which can be a tedious procedure.  It also helps reduce chemical waste in the real lab.  Finishing up our topic of naming and writing acid and base formulae, students will begin applying their knowledge of what makes a strong versus weak acid or base with the introduction of equilibrium at the end of the week.
titration method
                                              
Monday:
1.  Grade naming bases worksheet
2.  Start titration lab – unknown I
3.  Titration Virtual Labs due Tuesday
4.  quiz tomorrow over naming acids

Tuesday:
1.  quiz over naming acids
2.  quiz tomorrow over naming bases
3. continue titration lab – unknown I finish, start unknown II
4.  grade 22 pt titration worksheet Friday

Weds:
1.  quiz over naming bases
2.  finish titration lab – unknown II
3.  22 pt titration worksheet due Friday

Thurs:
1. finish titration lab
2. titration worksheets both due tomorrow
3.  quiz tomorrow over titration
4.  start acid/base review up to ICE tables due Monday

Friday: 
1.       Grade 22 pt titration worksheet
2.       Quiz over titration
3.       20 pt titration worksheet due
4.       Acid-Base Review up to ICE tables due Monday
5.       Equilibrium ICE table notes

AP Chemistry Lesson Plans March 24-28
We are finishing up our equilibrium unit this week and taking the AP practice test for it.  Equilibrium is a very important topic that is used in many different aspects of chemistry and will be revisited in the acid/base review as well as our thermodynamics review.  Our next topic of rates of reaction will be introduced next week, so students are asked to read ahead in their AP book.  On Friday, we will have a fun activity about the Periodic Table in the format of an NCAA bracket to celebrate March Madness!



Monday:
1.  homework back and discuss
2.  Ksp notes and problems lecture
3.  Ch 11 homework on rates due!

Tuesday:
1.  finish notes on Ksp
2.  Modern Chemistry prob set in class – due Thursday
3.  finish #2 free response in Cliffs

Weds:
1.  Cliff’s worksheet on equilibrium due Friday
2.  Problem set due tomorrow

Thurs:  PLAY DAY
1.  Prob set due
2.  AP equilibrium multiple choice and free response test

Friday: 
1.  Cliff’s worksheet due
2.  Element March Madness activity